The Journal of Organic Chemistry

Palladium-catalyzed reaction of N-allylbenzotriazoles with amines: A novel method for the preparation of allylamines

AR Katritzky, J Yao, M Qi

Index: Katritzky, Alan R.; Yao, Jiangchao; Qi, Ming Journal of Organic Chemistry, 1998 , vol. 63, # 15 p. 5232 - 5234

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Citation Number: 20

Abstract

Allylamines are common moieties in biologically active compounds1 and important intermediates in organic synthesis. Many syntheses of allylamines have been documented including (i) reaction of alkenyl cuprates with iminium salts, R-aminoethers or R- aminothioethers, 2 (ii) reaction of Grignard reagents with allyl-R-aminonitriles, 3 and (iii) the amination of dienes4 and allylic halides. 1a, 5 The most general approach is based on the ...