Alumina-catalyzed reactions of hydroxyarenes and hydroaromatic ketones. IV. Products and mechanism of reaction of 2-naphthol with methanol

LRH Klemm, CE Klopfenstein…

文献索引：Klemm,L.H. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 1069 - 1075

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被引用次数: 22

摘要

Results Results obtained are summarized in Table I. As in the case of l-naphthol12 the reaction of 2-naphthol with methanol yields four types of products in the temperature range studied, ie., methyl naphthyl ethers (3, 4), methylated naphthols (almost entirely 5), methylated oxo compounds (6, 7), and methylnaphthalenes (8-17). The change in the relative yields of these types of products as a function of temperature and catalyst acidity ...