Experimental analysis of the catalytic cycle of the borane-promoted imine reduction with hydrosilanes: Spectroscopic detection of unexpected intermediates and a …

J Hermeke, M Mewald, M Oestreich

文献索引：Ahlbrecht, Hubertus; Dueber, Ernst-Otto Synthesis, 1980 , # 8 p. 630 - 631

全文：HTML全文

被引用次数: 50

摘要

... only Si–H bonds (90 kcal/mol) but also the stronger H–H bond (108 kcal/mol) heterolytically, thereby even allowing for metal-free hydrogenation.(5, 6) Despite recent major efforts in these areas, there are just a handful of enantioselective variants of imine reductions(7, 8) and an ...