e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Experimental analysis of the catalytic cycle of the borane-promoted imine reduction with hydrosilanes: Spectroscopic detection of unexpected intermediates and a …
... only Si–H bonds (90 kcal/mol) but also the stronger H–H bond (108 kcal/mol) heterolytically, thereby even allowing for metal-free hydrogenation.(5, 6) Despite recent major efforts in these areas, there are just a handful of enantioselective variants of imine reductions(7, 8) and an ...
