The Journal of Organic Chemistry

Intramolecular Diels-Alder cycloadditions of perchloro (allyloxy)-and perchlorobis (allyloxy) cyclopentadienes

ME Jung, LA Light

文献索引：Jung, Michael E.; Light, Lynn A. Journal of Organic Chemistry, 1982 , vol. 47, # 6 p. 1084 - 1090

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被引用次数: 8

摘要

The intramolecular cycloadditions of some mono (ally1oxy)-and bis (ally1oxy) perchlorocyclopentadienes have been carried out. Even in the case of trisubstituted olefins, this internal cycloaddition process occurs in good yield. The allyloxy compounds (10, 11, 15, and 16) were prepared by treating hexachlorocyclopentadiene (9) with the corresponding allylic alcohol in basic solution. In only one case could the intermediate allyloxy diene be ...