Solvent-Free Synthesis of Tertiaryα-Hydroxyphosphates by the Triethylamine-Catalyzed Hydrophosphonylation of Ketones

C Wang, J Zhou, X Lv, J Wen, H He

文献索引：Wang, Chubei; Zhou, Jianwei; Lv, Xingbin; Wen, Junlei; He, Hongwu Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 10 p. 1334 - 1339

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被引用次数: 4

摘要

A new, environmentally benign, convenient, and easy method of synthesizing tertiary α-hydroxyphosphonates by the triethylamine-catalyzed hydrophosphonylation of unactivated ketones was developed. In the presence of triethylamine, aromatic or heteroaromatic ketones can react with phosphite to form tertiary α-hydroxyphosphonates under solvent-free and mild conditions. The proposed method was also suitable for functionalized ketones. ... A new, environmentally ...