Journal of the American Chemical Society

Photolysis of peresters. Reactions of alkoxy-alkyl radical pairs in solution

RA Sheldon, JK Kochi

文献索引：Sheldon,R.A.; Kochi,J.K. Journal of the American Chemical Society, 1970 , vol. 92, p. 5175 - 5186

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被引用次数: 35

摘要

Abstract: A series of peresters RC020C (SH3) 2R'cleanly liberate 1 mol of carbon dioxide with a quantum yield of unity when irradiated in solution at 2537 A. An alkyl radical R. and an alkoxy radical. OC (CH&R'are the first discernible intermediates. The electron spin resonance spectrum of the alkyl radical R. is obtainable when photolyses are carried out directly in the cavity of the spectrometer. The esr spectrum of R'. from the secondary ...