Solvomercuration-demercuration. 12. The solvomercuration-demercuration of olefins in alcohol solvents with mercuric trifluoroacetate-an ether synthesis of wide …

…, JT Kurek, MH Rei, KL Thompson

文献索引：Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L. Journal of Organic Chemistry, 1985 , vol. 50, # 8 p. 1171 - 1174

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被引用次数: 10

摘要

Studies on the solvomercuration-demercuration (SM-DM) of olefins in methyl, ethyl, isopropyl, and tert-butyl alcohols with mercuric trifluoroacetate have been extended. 1- Dodecene undergoes the SM-DM sequence with typical results for a monosubstituted olefin. Cyclopentene similarly exhibited behavior characteristic of a 1, 2-disubstituted olefin in methanol, ethanol, and 2-propanol, giving high yields,> 90% of the corresponding ethers. ...