Journal of the American Chemical Society

Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties

JM Berg, RH Holm

文献索引：Berg, Jeremy M.; Holm, R. H. Journal of the American Chemical Society, 1985 , vol. 107, # 4 p. 917 - 925

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被引用次数: 166

摘要

Abstract: Development of models for the active sites of oxo-transfer molybdoenzymes has been initiated. Suitable models should be capable of oxygen atom transfer to or from the substrate, approach the native coordination unit, and be inert to formation of pox0 Mo (V) dimers. Toward this end, the sterically hindered ligands 2, 6-bis (2, 2-diphenyl-2- hydroxyethyl) pyridine (LN (OH),) and 2, 6-bis (2, 2-diphenyl-2-mercaptoethanyl) pyridine ( ...