Journal of the American Chemical Society

Synthetic approach to the mononuclear active sites of molybdoenzymes: catalytic oxygen atom transfer reactions by oxomolybdenum (IV, VI) complexes with …

JM Berg, RH Holm

文献索引：Berg, Jeremy M.; Holm, R. H. Journal of the American Chemical Society, 1984 , vol. 106, p. 3035 - 3036

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被引用次数: 76

摘要

The mononuclear active sites of certain molybdoen~ ymes~~~ that catalyze oxygen atom transfer reactions are becoming increasingly defined structurally from chemical, EPR, 4 and Mo EXAFS5s6 results. Sulfite oxidase, for example, appears to have the (minimal) coordination units MoV1O2S2,,(N/0) and MoIVOS3 in its oxidized and fully reduced forms, 6 respectively. Credible synthetic representations of such sites must, inter alia,(i) approach ...