Applied Catalysis A: General

An efficient method for the transformation of naturally occurring monoterpenes into amines through rhodium-catalyzed hydroaminomethylation

DS Melo, SS Pereira-Júnior, EN Dos Santos

文献索引：Melo, Daniela S.; Pereira-Junior, Schubert S.; Dos Santos, Eduardo N. Applied Catalysis A: General, 2012 , vol. 411-412, p. 70 - 76

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被引用次数: 9

摘要

The hydroaminomethylation (hydroformylation/reductive amination) of the naturally occurring monoterpenes, ie, limonene, camphene, and β-pinene, was studied having as condensation counterparts the amines di-n-butylamine, morpholine or n-butylamine. Moderate to good yields (75–94%) were obtained employing [Rh (cod)(μ-OMe)] 2 as pre- catalyst in the presence or not of triphenylphosphine or tribenzylphosphine as ancillaries ...