The hydroaminomethylation (hydroformylation/reductive amination) of the naturally occurring monoterpenes, ie, limonene, camphene, and β-pinene, was studied having as condensation counterparts the amines di-n-butylamine, morpholine or n-butylamine. Moderate to good yields (75–94%) were obtained employing [Rh (cod)(μ-OMe)] 2 as pre- catalyst in the presence or not of triphenylphosphine or tribenzylphosphine as ancillaries ...