Tetrahedron

The organoselenium-mediated reduction of α, β-epoxy ketones, α, β-epoxy esters, and their congeners to β-hydroxy carbonyl compounds: Novel methodologies for …

M Miyashita, T Suzuki, M Hoshino, A Yoshikoshi

文献索引：Miyashita, Masaaki; Suzuki, Toshio; Hoshino, Masahide; Yoshikoshi, Akira Tetrahedron, 1997 , vol. 53, # 37 p. 12469 - 12486

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被引用次数: 115

摘要

Novel methods for the reduction of α, β-epoxy ketones, α, β-epoxy esters (glycidic esters), and their congeners to β-hydroxy carbonyl compounds (aldols) by the use of organoselenium reagents are described. The reagents, a sodium phenylseleno (triethyl) borate complex Na [PhSeB (OEt) 3] easily prepared by reduction of (PhSe) 2 with NaBH4 in EtOH and benzeneselenol (PhSeH) generated in situ from the borate complex by addition ...