An efficient synthesis of (Z)-γ-fluoroallylphosphonates using a base-promoted deconjugation of (E)-γ-fluorovinylphosphonates, and its utility as fluoroolefin-containing …
GB Hammond
文献索引：Hammond, Gerald B.; Demendonca, Daniel J. Journal of Fluorine Chemistry, 2000 , vol. 102, # 1-2 p. 189 - 197
A three-step synthesis of γ-fluoroallylphosphonates starting with α, β-unsaturated aldehydes is described. Treatment with diethyl phosphite in the presence of KF gives α-hydroxyallyl phosphonate in excellent yield; DAST deoxofluorination produces the corresponding γ-
