Kinetics and mechanism of electron??transfer reaction of aquothallium (III) and coordinated thallium (III). Oxidation of metol with thallium (III) in acid perchlorate medium
S Nahar, PD Sharma
文献索引:Nahar, Sharmila; Sharma, P. D. Journal of Physical Organic Chemistry, 1994 , vol. 7, # 3 p. 117 - 121
Abstract The kinetics of oxidation of metol (N-methyl-p-aminophenol) by thallium (III) have been studied in a perchloric acid medium. This organic compound is employed extensively in photographic work. The stoichiometry of the reaction is represented by: C 6 H 4 (OH) NHCH 3+ TI III→ C 6 H 4 (O) NCH 3+ TI I+ 2H+ The kinetics indicate the rate law: