Synthesis, spectral and structural characterization of Ni (II), Cu (II), Zn (II), Cd (II) and Hg (II) complexes with 2-mercapto-5-methyl-1, 3, 4-thiadiazole: A Zn (II) complex …
P Bharati, A Bharti, MK Bharty, S Kashyap, UP Singh…
Abstract Five new complexes,[Ni (mthd) 2 (py) 2](1),[Cu (en) 2](mthd) 2 (2),[H 2 en][Hg (mthd) 3] 2· 2H 2 O (3),[Cd (mthd) 2 (o-phen) 2] 2· H 2 O (4) and [Zn (mthd) 2 (bpy)](5)(Hmthd= 2-mercapto-5-methyl-1, 3, 4-thiadiazole), have been synthesized. All the complexes have been fully characterized by various techniques: elemental analyses, IR, electronic and fluorescent spectral data. The ligand is present in the deprotonated thiol ...
