The Journal of Organic Chemistry

Alkoxyphosphonium salts. 4. Kinetics and mechanisms of Arbuzov reactions

ES Lewis, D Hamp

文献索引：Lewis, Edward S.; Hamp, Donald Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 2025 - 2029

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被引用次数: 13

摘要

Results The study of kinetics on phosphorus compounds has been complicated by several factors. Side reactions such as oxidation of trivalent compounds and hydrolysis of various esters (including especially the alkoxyphosphonium compounds) are sometimes serious. Thus a satisfactory analytical method subject to interference by side reactions such as conductivity, dilatometry, and to a considerable extent infrared are not wholly reliable. Few ...