Possible evidence for a new mechanism for reaction of trimethylphosphine with dioxygen

HD Burkett, WE Hill, SD Worley

文献索引：Burkett, H. D.; Hill, W. E.; Worley, S. D. Phosphorus and Sulfur and the Related Elements, 1984 , vol. 20, p. 169 - 172

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被引用次数: 12

摘要

Abstract Evidence is presented suggesting that the mechanism for reaction of trimethylphosphine with dioxygen proceeds through Me3PO2 as an intermediate. A mechanistic scheme is proposed to explain the products observed and the spectroscopic data obtained.