The role of tosylhydrazone stereochemistry upon the regiospecificity of olefin formation

WG Dauben, GT Rivers…

文献索引：Dauben,W.G. et al. Journal of the American Chemical Society, 1977 , vol. 99, # 10 p. 3414 - 3420

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被引用次数: 20

摘要

Abstract: The isomeric pulegone p-toluenesulfonylhydrazones (tosylhydrazones), 5-E and 5- Z, have been prepared and their structures have been established by x-ray crystallographic techniques. The alkyllithium mediated decomposition of these isomeric tosylhydrazones has been studied in order to evaluate the role of tosylhydrazone stereochemistry upon the regiospecificity of olefin formation. Significantly, decomposition of the isomeric ...