Copper-catalyzed atom transfer radical addition (ATRA) and cyclization (ATRC) reactions in the presence of environmentally benign ascorbic acid as a reducing agent
MJW Taylor, WT Eckenhoff, T Pintauer
文献索引：Taylor, Matthew J. W.; Eckenhoff, William T.; Pintauer, Tomislav Dalton Transactions, 2010 , vol. 39, # 47 p. 11475 - 11482
In recent years, copper-catalyzed atom transfer radical addition (ATRA) has emerged as a viable organic procedure for the formation of carbon–carbon bonds starting from alkyl halides and alkenes. Studies have primarily focused on the use of free-radical initiators to regenerate the copper (I) complex or activator in situ. Although these initiators led to a significant decrease in the amount of metal catalyst, they were much less effective for ...
