Oxidation of caffeine with hydrogen peroxide catalyzed by metalloporphyrins

…, MMQ Simões, ICMS Santos, FMJ Domingues…

文献索引：Neves, Claudia M.B.; Simoes, Mario M.Q.; Santos, Isabel C.M.S.; Domingues, Fernando M.J.; Neves, M. Graca P.M.S.; Almeida Paz, Filipe A.; Silva, Artur M.S.; Cavaleiro, Jose A.S. Tetrahedron Letters, 2011 , vol. 52, # 22 p. 2898 - 2902

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被引用次数: 23

摘要

Abstract The biomimetic oxidation of caffeine with hydrogen peroxide using metalloporphyrins as catalysts, which are known to be good biomimetic models of cytochrome P450 enzymes, is investigated. The two manganese porphyrins tested, chloro [5, 10, 15, 20-tetrakis (2, 6-dichlorophenyl) porphyrinato] manganese (III),[Mn (TDCPP) Cl], and chloro [5, 10, 15, 20-tetrakis (pentafluorophenyl) porphyrinato] manganese (III),[Mn ( ...