Tetrahedron Letters

Synthesis of the spiroacetal parts of spirofungin A and B

Y Shimizu, H Kiyota, T Oritani

文献索引：Shimizu, Yuko; Kiyota, Hiromasa; Oritani, Takayuki Tetrahedron Letters, 2000 , vol. 41, # 17 p. 3141 - 3144

全文：HTML全文

被引用次数: 19

摘要

The C9–C20 spiroacetal parts of spirofungin A and B, antifungal antibiotics from Streptomyces violaceusniger Tü 4113, were synthesized simultaneously from (S)-citronellyl bromide and (±)-epoxy alcohol via alkyne–lactone coupling reaction and diastereomeric separation.