Synthesis of Optically Pure Diglycerol Tetraether Model Lipids with Non??Natural Branching Pattern

…, A Meister, G Hause, A Blume, B Dobner

文献索引：Markowski, Thomas; Drescher, Simon; Meister, Annette; Hause, Gerd; Blume, Alfred; Dobner, Bodo European Journal of Organic Chemistry, 2011 , # 29 p. 5894 - 5904

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被引用次数: 8

摘要

Abstract Three new, chain-modified, optically pure diglycerol tetraether lipids with one membrane-spanning chain have been synthesised. These lipids contain a different number and constitution of the methyl branches connected to the hydrophobic chains as compared with natural archaeal or other previously synthesised lipids. The correct chirality of the branched alkyl chain was introduced starting from commercially available (S)-citronellyl ...