Fluorodesulfurization. A new reaction for the formation of carbon-fluorine bonds

J Kollonitsch, S Marburg…

文献索引：Kollonitsch,J. et al. Journal of Organic Chemistry, 1976 , vol. 41, p. 3107 - 3111

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被引用次数: 55

摘要

Discussion The chlorinolytic cleavage of carbon-sulfur (CS) bonds is well documented and a CS bond rupture effected by bromine has been suggested but no carbon-fluorine bonds have been made by this route. Compounds in the cysteine-cystine system have been converted to their 3-chloroalanine analogues. lb, c These reactions were carried out with suspensions of hydrochlorides in methylene chloride and their mechanistic relevance to ...