Asymmetric catalysis of the friedel-crafts reaction with fluoral by chiral binaphthol-derived titanium catalysts through asymmetric activation

A Ishii, VA Soloshonok, K Mikami

文献索引：Ishiit, Akihiro; Soloshonok, Vadim A.; Mikami, Koichi Journal of Organic Chemistry, 2000 , vol. 65, # 5 p. 1597 - 1599

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被引用次数: 101

摘要

Asymmetric synthesis of organofluorine compounds is an important issue in pharmaceutical chemistry1 and optoelectronic material science. 2 In particular, asymmetric catalysis of carbon-carbon bond forming reactions is the most attractive method, because the carbon skeleton of chiral organofluorine molecules can be constructed at the time of asymmetric induction. 3 The Friedel-Crafts (FC) reaction is one of the most fundamental carbon- ...