The Journal of Organic Chemistry

Oxidative cleavage of ethers by metallic nitrates supported on silica gel

T Nishiguchi, M Bougauchi

文献索引：Nishiguchi, Takeshi; Bougauchi, Masahiro Journal of Organic Chemistry, 1990 , vol. 55, # 21 p. 5606 - 5609

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被引用次数: 26

摘要

Metallic nitrates supported on silica gel efficiently cleave and oxidize ethers to the corresponding aldehydes or ketones under mild conditions. Silica gel is essential for the efficient oxidation, and CU (NO~)~ and ZII (NO~)~ are suitable for practical use. Overoxidation of the product aldehydes is not observed. In some cases alkyl nitrites are isolated in addition to the carbonyl compounds, and the decomposition of alkyl nitrites to ...