Novel and Highly Selective Conversion of Alcohols and Thiols to Alkyl Nitrites with Triphenylphosphine/2, 3-Dichloro-5, 6-dicyanobenzoquinone/Bu4 NNO2 System
B Akhlaghinia, AR Pourali
文献索引：Akhlaghinia, Batool; Pourali, Ali Reza Synthesis, 2004 , # 11 p. 1747 - 1749
Abstract Alkyl nitrites were prepared in good to excellent yields by treatment of alcohols and thiols with triphenylphosphine/2, 3-dichloro-5, 6-dicyanobenzoquinone/Bu 4 NNO 2 in acetonitrile. This method is highly selective for the conversion of primary alcohols to alkyl nitrites in the presence of secondary and tertiary alcohols and thiols.
