Synthetic Communications

Reduction of isophorone with sodium borohydride: change in regioselectivity with hydrotropes

M Laxman, MM Sharma

文献索引：Laxman, Mahalaxmi; Sharma, Man Mohan Synthetic Communications, 1990 , vol. 20, # 1 p. 111 - 117

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被引用次数: 20

摘要

ABSTRACT : Preferential 1,4- reduction of isophorone by sodium borohydride occurs in the presence of hydrotropes such as polyalkylene glycols. An anomalous effect of temperature was also observed using sodium salicylate as hydrotrope. ... Since the pioneering work of Neuberg', the term hydrotropy has been used to ... Very recently, a minimum hydrotrope concentration has been proposed5, formally ... Figure 1 : Reduction of isophorone by sodium borohydride