Abstract The fact was established that the pyrolysis of gaseous iodomethanes RI yields methane and non traces of recombination products R2. A pyrolysis mechanism was proposed and rate constants of limiting stages of the pyrolysis of iodomethane, trideuteroiodomethane, and diiodomethane over the range of 500–1500 K were determined.
[Slaughter, Legrande M.; Wolczanski, Peter T.; Klinckman, Thomas R.; Cundari, Thomas R. Journal of the American Chemical Society, 2000 , vol. 122, # 33 p. 7953 - 7975]