Aldehydes from dihydro-1, 3-oxazines. II. Synthesis of. alpha.,. beta.-unsaturated aldehydes and their C-1 deuterated derivatives

AI Meyers, A Nabeya, HW Adickes…

文献索引：Meyers,A.I. et al. Journal of the American Chemical Society, 1969 , vol. 91, p. 764 - 765

被引用次数: 34

摘要

Journal of the American Cliemicul Society 1 91: 3 1 Junuarj 29, cursors to a variety of aliphatic aldehydes. We now wish to describe the reaction of these oxazine anions with a host of carbonyl compounds, giving rise to good yields of the adducts, 2, which are useful precursors to conjugated aldehydes. Addition of aldehydes or ketones to the THF solution of the lithio salt of 1 (a or b) at-78'followed by hydrolytic work-up produces near quantitative ...

Practical Stereoselective Synthesis of (2 E)??and (2 Z)??4??...

[Karagiozov, Stoyan K.; Abbott, Frank S. Synthetic Communications, 2004 , vol. 34, # 5 p. 871 - 888]

Dienamines as Diels-Alder dienes. An efficient cyclohexannul...

[Snowden, Roger L.; Wuest, Manfred Tetrahedron Letters, 1986 , vol. 27, # 6 p. 699 - 702]

Dilithiated 3-tosylpropanal dimethyl acetal as β, β-acylviny...

[Bonete, Pedro; Najera, Carmen Tetrahedron, 1996 , vol. 52, # 11 p. 4111 - 4122]

Synthesis of aldehydes from dihydro-1, 3-oxazines

[Meyers,A.I. et al. Journal of Organic Chemistry, 1973 , vol. 38, p. 36 - 56]