Tetrahedron

Direct ionic chlorination of alkyl sulfones with sulfuryl chloride

I Tabushi, Y Tamaru, Z Yoshida

文献索引：Tabushi,I. et al. Tetrahedron, 1974 , vol. 30, p. 1457 - 1463

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被引用次数: 4

摘要

The introduction of a Cl atom usually takes place at a position a to the α atom of alkyl sulfones. In this paper, a new ionic chlorination method of alkyl sulfones with sulfuryl chloride in which the most noteworthy observation was exclusive or highly selective β- chlorination of diethyl sulfone or sulfolane (tetrahydrothiophene-1, 1-dioxide) is described. The most successful synthetic application of this method was exemplified by the ...