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Locus-specific microemulsion catalysts for sulfur mustard (HD) chemical warfare agent decontamination

…, SJ Mitchell, S Notman, JA Platts, J Riches…

文献索引:Fallis, Ian A.; Griffiths, Peter C.; Cosgrove, Terence; Dreiss, Cecile A.; Govan, Norman; Heenan, Richard K.; Holden, Ian; Jenkins, Robert L.; Mitchell, Stephen J.; Notman, Stuart; Platts, Jamie A.; Riches, James; Tatchell, Thomas Journal of the American Chemical Society, 2009 , vol. 131, # 28 p. 9746 - 9755

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被引用次数: 23

摘要

The rates of catalytic oxidative decontamination of the chemical warfare agent (CWA) sulfur mustard (HD, bis (2-chlororethyl) sulfide) and a range (chloroethyl) sulfide simulants of variable lipophilicity have been examined using a hydrogen peroxide-based microemulsion system. SANS (small-angle neutron scattering), SAXS (small-angle X-ray scattering), PGSE- NMR (pulsed-gradient spin− echo NMR), fluorescence quenching, and electrospray mass ...