Di-and Tri-2-furoylmethane

GS Hammond, FS Schultz

文献索引：Hammond; Schultz Journal of the American Chemical Society, 1952 , vol. 74, p. 329,331

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被引用次数: 2

摘要

Di-and tri-2-furoylmethane have been identified as by-products in the synthesis of 2- acetylfuran by the reaction of furoyl chloride with dimethylcadmium. The compounds have also been prepared by conventional synthetic procedures. The near ultraviolet absorption spectra of the new ketones indicate that both are highly enolized in ethanol solutions. The spectra of the enolate anions are strikingly similar to those of the enols. This appears to be ...