Intermolecular hydrophosphination of alkynes and related carbon-carbon multiple bonds catalyzed by organoytterbiums

…, K Komeyama, M Takeda, T Shishido…

文献索引：Takaki, Ken; Koshoji, Go; Komeyama, Kimihiro; Takeda, Mitsuhiro; Shishido, Tetsuya; Kitani, Akira; Takehira, Katsuomi Journal of Organic Chemistry, 2003 , vol. 68, # 17 p. 6554 - 6565

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被引用次数: 85

摘要

Intermolecular hydrophosphination of alkynes with diphenylphosphine is catalyzed by a Yb- imine complex,[Yb (η2-Ph2CNPh)(hmpa) 3], to give alkenylphosphines and phosphine oxides after oxidative workup in good yields under mild conditions. This reaction is also ...