甲基苯乙烯

常用名 甲基苯乙烯 英文名 Trans-1-Phenyl-1-Propene
CAS号 873-66-5 分子量 118.176
密度 0.9±0.1 g/cm3 沸点 167.5±0.0 °C at 760 mmHg
分子式 C9H10 熔点 N/A
MSDS甲基苯乙烯的MSDS|SDS|pdf下载 N/A 闪点 60.0±0.0 °C

 甲基苯乙烯物理化学性质

[ 密度 ]: 0.9±0.1 g/cm3
[ 沸点 ]: 167.5±0.0 °C at 760 mmHg
[ 分子式 ]: C9H10
[ 分子量 ]: 118.176
[ 闪点 ]: 60.0±0.0 °C
[ 精确质量 ]: 118.078247
[ LogP ]: 3.22
[ 蒸汽压 ]: 2.2±0.1 mmHg at 25°C
[ 折射率 ]: 1.560
[ 储存条件 ]:

密封冷藏,温度:4ºC

[ 稳定性 ]:

1. 常温常压下稳定,避免氧化物接触

2. 存在于烟气中。

[ 分子结构 ]:

1、 摩尔折射率:42.14

2、 摩尔体积(cm3/mol):130.4

3、 等张比容(90.2K):310.2

4、 表面张力(dyne/cm):32.0

5、 介电常数(F/m):2.79

6、 极化率(10-24cm3):16.70

[ 计算化学 ]:

1、 疏水参数计算参考值(XlogP):3.2

2、 氢键供体数量:0

3、 氢键受体数量:0

4、 可旋转化学键数量:1

5、 拓扑分子极性表面积(TPSA):0

6、 重原子数量:9

7、 表面电荷:0

8、 复杂度:86.2

9、 同位素原子数量:0

10、 确定原子立构中心数量:0

11、 不确定原子立构中心数量:0

12、 确定化学键立构中心数量:1

13、 不确定化学键立构中心数量:0

14、 共价键单元数量:1

[ 更多 ]:

1. 性状:未确定

2. 密度(g/mL,25/4℃):0.9023

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):-29.3

5. 沸点(ºC,常压):178~180

6. 沸点(ºC,5.2kPa):未确定

7. 折射率(n 20/D): 1.5506

8. 闪点(ºC):52

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定

 甲基苯乙烯MSDS

反式-β-甲基苯乙烯 (含稳定剂TBC)

模块1. 化学品
产品名称: trans-β-Methylstyrene (stabilized with TBC)

模块2. 危险性概述
GHS分类
 物理性危害
易燃液体 第3级
 健康危害
皮肤腐蚀/刺激 第2级
严重损伤/刺激眼睛 2A类
 环境危害
急性水生毒性 第2级
慢性水生毒性 第2级
GHS标签元素
 图标或危害标志
 信号词警告
 危险描述易燃液体和蒸气
造成皮肤刺激
造成严重眼刺激
对水生生物有毒性
长期影响对水生生物有毒性
 防范说明
[预防] 远离热源/火花/明火/热表面。禁烟。
保持容器密闭。
使用防爆的电气/通风/照明设备。采取预防措施以防静电和火花引起的着火。
避免释放到环境中。
处理后要彻底清洗双手。
穿戴防护手套/护目镜/防护面具。
反式-β-甲基苯乙烯 (含稳定剂TBC)

模块2. 危险性概述
[急救措施]眼睛接触:用水小心清洗几分钟。如果方便,易操作,摘除隐形眼镜。继续冲洗。
眼睛接触:求医/就诊
皮肤接触:立即去除/脱掉所有被污染的衣物。用水清洗皮肤/淋浴。
若皮肤刺激:求医/就诊。
脱掉被污染的衣物,清洗后方可重新使用。
收集溢出物。
[储存]存放于通风良好处。保持凉爽。
[废弃处置] 根据当地政府规定把物品/容器交与工业废弃处理机构。
其他没有分类的危险可能引起聚合。

模块3. 成分/组成信息
单一物质/混和物单一物质
化学名(中文名): 反式-β-甲基苯乙烯 (含稳定剂TBC)
百分比: >97.0%(GC)
CAS编码: 873-66-5
俗名: trans-1-Phenyl-1-propene (stabilized with TBC) , trans-Propenylbenzene
(stabilized with TBC)
分子式: C9H10

模块4. 急救措施
吸入: 将受害者移到新鲜空气处,保持呼吸通畅,休息。若感不适请求医/就诊。
皮肤接触: 立即去除/脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。
若皮肤刺激或发生皮疹:求医/就诊。
眼睛接触:用水小心清洗几分钟。如果方便,易操作,摘除隐形眼镜。继续清洗。
如果眼睛刺激:求医/就诊。
食入: 若感不适,求医/就诊。漱口。
危害迹象: 咳嗽, 咽喉痛, 发红
紧急救助者的防护:救援者需要穿戴个人防护用品,比如橡胶手套和气密性护目镜。

模块5. 消防措施
合适的灭火剂:干粉,泡沫,二氧化碳
不适用的灭火剂:水(有可能扩大灾情。)
特殊危险性:该物质受热或着火可能爆聚。受热容器可能爆炸。从受保护的位置灭火。
特定方法:从上风处灭火,根据周围环境选择合适的灭火方法。
非相关人员应该撤离至安全地方。
周围一旦着火:喷水,保持容器冷却。如果安全,消除一切火源。
消防员的特殊防护用具:灭火时,一定要穿戴个人防护用品。

模块6. 泄漏应急处理
个人防护措施,防护用具, 使用个人防护用品。远离溢出物/泄露处并处在上风处。确保足够通风。
紧急措施:泄露区应该用安全带等圈起来,控制非相关人员进入。
环保措施:小心,切勿排入河流等。因为考虑对环境有负面影响。
控制和清洗的方法和材料:回收到带盖容器前用干砂或惰性吸收剂吸收泄漏物。一旦大量泄漏,筑堤控制。附着
物或收集物应该根据相关法律法规废弃处置。
副危险性的防护措施移除所有火源。一旦发生火灾应该准备灭火器。使用防火花工具和防爆设备。

模块7. 操作处置与储存
处理
反式-β-甲基苯乙烯 (含稳定剂TBC)

模块7. 操作处置与储存
技术措施: 在通风良好处进行处理。穿戴合适的防护用具。防止烟雾产生。远离热源/火花/明火
/热表面。禁烟。采取措施防止静电积累。使用防爆设备。处理后彻底清洗双手和脸。
注意事项:如果可能,使用封闭系统。如果蒸气或浮质产生,使用通风、局部排气。
操作处置注意事项:避免接触皮肤、眼睛和衣物。
贮存
储存条件:保持容器密闭。存放于冷藏防爆冰箱。
远离不相容的材料比如氧化剂存放。
热敏
包装材料:依据法律。

模块8. 接触控制和个体防护
工程控制:尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。
个人防护用品
 呼吸系统防护:防毒面具。依据当地和政府法规。
 手部防护:防护手套。
 眼睛防护:安全防护镜。如果情况需要,佩戴面具。
 皮肤和身体防护:防护服。如果情况需要,穿戴防护靴。

模块9. 理化特性
液体
外形(20°C):
外观:透明
颜色: 无色-微浅黄色
气味:无资料
pH:无数据资料
熔点: -29°C
沸点/沸程 176 °C
闪点: 52°C
爆炸特性
 爆炸下限: 0.9%
 爆炸上限:无资料
蒸气压: 0.2kPa/25°C
蒸气密度: 4.1
密度: 0.91
溶解度:
[水] 不溶于(0.01g/100mL, 25°C)
[其他溶剂]无资料
log水分配系数 = 3.31

模块10. 稳定性和反应性
化学稳定性:在热、光影响下或与聚合引发剂比如过氧化物等接触可能发生聚合。
危险反应的可能性:未报道特殊反应性。
避免接触的条件: 热, 火花, 明火, 静电, 光
须避免接触的物质氧化剂
危险的分解产物: 一氧化碳, 二氧化碳

模块11. 毒理学信息
急性毒性: ivn-mus LD50:56 mg/kg
对皮肤腐蚀或刺激:无资料
对眼睛严重损害或刺激:无资料
反式-β-甲基苯乙烯 (含稳定剂TBC)

模块11. 毒理学信息
生殖细胞变异原性: sce-hmn-lym 1 mmol/L
致癌性:
IARC =无资料
NTP =无资料
生殖毒性:无资料
RTECS 号码: DA8400500

模块12. 生态学信息
生态毒性:
鱼类:无资料
甲壳类:无资料
藻类:无资料
残留性 / 降解性:无资料
潜在生物累积 (BCF):无资料
土壤中移动性
 log水分配系数: 3.31
 土壤吸收系数 (Koc):无资料
 亨利定律无资料
constant(PaM3/mol):

模块13. 废弃处置
如果可能,回收处理。请咨询当地管理部门。建议在装有后燃和洗涤装置的化学焚烧炉中焚烧。废弃处置时请遵守
国家、地区和当地的所有法规。

模块14. 运输信息
联合国分类: 第3类 易燃液体 。
UN编号: 3295
正式运输名称: 碳氢化合物, 液体, 不另作详细说明
包装等级: III
海洋污染物: Y

模块15. 法规信息
《危险化学品安全管理条例》(2002年1月26日国务院发布,2011年2月16日修订): 针对危险化学品的安全使用、
生产、储存、运输、装卸等方面均作了相应的规定。


模块16 - 其他信息
N/A

 甲基苯乙烯毒性和生态

甲基苯乙烯毒理学数据:

急性毒性:小鼠静脉LD50:56mg/kg

甲基苯乙烯生态学数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DA8400500
CHEMICAL NAME :
Benzene, propenyl-, (E)-
CAS REGISTRY NUMBER :
873-66-5
BEILSTEIN REFERENCE NO. :
1361672
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H10
MOLECULAR WEIGHT :
118.19
WISWESSER LINE NOTATION :
2U1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
1 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 116,379,1983

 甲基苯乙烯安全信息

[ 危害码 (欧洲) ]: Xn: Harmful;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]: R36/37/38
[ 安全声明 (欧洲) ]: S16-S26-S36/37/39-S61-S62
[ 危险品运输编码 ]: UN 2618 3/PG 3
[ WGK德国 ]: 2
[ RTECS号 ]: DA8400500
[ 包装等级 ]: III
[ 危险类别 ]: 3.2

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