Tetrahedron

Phospholin-derivate aus phosphor-trihalogeniden und dienen

U Hasserodt, K Hunger, F Korte

文献索引：Hasserodt,U. et al. Tetrahedron, 1963 , vol. 19, p. 1563 - 1575

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被引用次数: 52

摘要

1, 1, 1-Trihalophospholines can be prepared from dienes and phosphorus trihalides. Phosphinic and thiophosphinic acid derivatives, respectively, have been obtained by solvolysis of these compounds, whereas 1-oxo-1-chlorophospholines resulted from acetanhydride or sulfur dioxide treatment. The latter products have been converted to phosphine oxides by Grignard-compounds. The reaction described is simpler and more ...