Stereospecific Reactions of Nucleophilic Agents with Acetylenes and Vinyl-type Halides. VII. The Mechanism of the Base-catalyzed Reaction of Trichloroethylene with …

WE Truce, R Kassinger

文献索引：Truce; Kassinger Journal of the American Chemical Society, 1958 , vol. 80, p. 1916,1918, 1919

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被引用次数: 20

摘要

Previous work in this Laboratory2,* has indicated that reactions of nucleophilic agents with halogenated ethylenes may proceed by at least two different mechanisms,;. e., either initial p- elimination to form an acetylenic intermediate followed by nucleophilic addition, or initial nucleophilic addition to form a saturated intermediate or an incipient carbanion followed by elimination of HX or X-, respectively. Which path is followed will be determined in large ...