前往化源商城

Binding of dihydroxybenzenes in a synthetic molecular clip. Effect of hydrogen bonding and. pi.-stacking

RP Sijbesma, APM Kentgens…

文献索引:Sijbesma, Rint P.; Kentgens, Arno P. M.; Nolte, Roeland J. M. Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3199 - 3201

全文:HTML全文

被引用次数: 57

摘要

Summary: A synthetic host, which can easily be assembled starting from urea and benzil, selectively binds resorcinol by hydrogen bonding and r-stacking. ... Exploring the potentialities of ur interactions and hydrogen bonding in order to attain strong and selective binding is currently an area of intense interest in host- guest chemistry. Rebek' and Hamilton2 have shown that a single aromatic surface can significantly improve the complexation of a guest in a hydrogen bonding receptor. ...