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Journal of the American Chemical Society

Intermolecular-Intramolecular Polymerization of α-Diolefins by Metal Alkyl Coördination Catalysts1

CS Marvel, JK Stille

文献索引:Marvel; Stille Journal of the American Chemical Society, 1958 , vol. 80, p. 1740,1742

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被引用次数: 139

摘要

The a-diolefins 1, 6-heptadiene, 1, 5-hexadiene and 2, 5-dimethyl-1, 5-hexadiene have been polymerized by metal alkyl coordination catalysts to yield soluble polymers which are believed to contain carbocyclic rings in the polymer chaiu. Poly-1, 6-heptadiene has been dehydrogenated to yield a polymer which shows aromatic and ineta substitution absorption in the infrared region and absorption for a benzene nucleiis ill the ultraviulet regioii. h new ...