Influences on the relative rates for CN bond-forming reductive elimination and β-hydrogen elimination of amides. A case study on the origins of competing reduction in …
JF Hartwig, S Richards, D Barañano…
文献索引：Hartwig, John F.; Richards, Steven; Baranano, David; Paul, Frederic Journal of the American Chemical Society, 1996 , vol. 118, # 15 p. 3626 - 3633
Typical decomposition by β-hydrogen elimination has limited the productive catalytic organometallic chemistry of late transition metal amido complexes. However, one reaction that has been shown to involve a late metal amido complex with β-hydrogens and elude extensive β-hydrogen elimination is the palladium-catalyzed amination of aryl bromides to give arylamines. The primary side products formed in these catalytic aminations are ...
