Journal of Organometallic Chemistry

Nickel (II) induzierte CC-verknüpfung zwischen kohlenmonoxid und alkinen unter erhalt der dreifachbindung

H Hoberg, HJ Riegel

文献索引：Hoberg, Heinz; Riegel, Hans Josef Journal of Organometallic Chemistry, 1983 , vol. 241, # 2 p. 245 - 250

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被引用次数: 0

摘要

Abstract Acetylene and 1-alkynes react with carbon monoxide under basic conditions (amines) with nickel (II) complexes. L 2 NiBr 2 (L= Et 2 NH,(C 6 H 5) 3 P), to give acetylencarboxamides with maintenance of the triple bond. Intermediates are isolated, characterised and a mechanism is proposed.