Ultrafast Photochemistry of Copper (II) Monochlorocomplexes in Methanol and Acetonitrile by Broadband Deep-UV-to-Near-IR Femtosecond Transient Absorption …
AS Mereshchenko, PK Olshin…
文献索引：Nilov, Denis I.; Komarov, Dmitry Y.; Panov, Maxim S.; Karabaeva, Kanykey E.; Mereshchenko, Andrey S.; Tarnovsky, Alexander N.; Wilson, R. Marshall Journal of the American Chemical Society, 2013 , vol. 135, # 9 p. 3423 - 3438
Photochemistry of copper (II) monochlorocomplexes in methanol and acetonitrile solutions is studied by UV-pump/broadband deep-UV-to-near-IR probe femtosecond transient absorption spectroscopy. Upon 255 and 266 nm excitation, the complexes in acetonitrile and methanol, respectively, are promoted to the excited ligand-to-metal charge transfer (LMCT) state, which has a short (sub-250 fs) lifetime. From the LMCT state, the complexes ...
