A study of the gas-phase interconversion of 1-(2-aryloxyphenyl) alkaniminyl and 2-(aryliminomethyl) phenoxyl radicals

M Black, JIG Cadogan, R Leardini, H McNab…

文献索引：Black, Michael; Cadogan; Leardini, Rino; McNab, Hamish; McDougald, Graham; Nanni, Daniele; Reed, David; Zompatori, Alberto Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 11 p. 1825 - 1832

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摘要

Flash vacuum pyrolysis of the allyl ethers 9–11 and of the oxime ethers 15–17 at 650° C (5× 10–2–5× 10–3 Torr) generates 2-(aryliminomethyl) phenoxyl radicals 4 and 1-(2- aryloxyphenyl) alkaniminyl radicals 5 respectively which can interconvert via a spirodienyl radical leading to common products which are generally