Journal of Organometallic Chemistry

Phase-transfer catalysis in cobalt catalyzed carbonylation of secondary benzyl halides

F Francalanci, M Foa

文献索引：Francalanci, F.; Foa, M. Journal of Organometallic Chemistry, 1982 , vol. 232, # 1 p. 59 - 70

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被引用次数: 38

摘要

Summary Application of the phase-transfer technique to the cobalt carbonyl-catalyzed carbonylation of secondary benzyl halides gives either monocarbonyl and double carbonyl insertion or coupling of organic halides as the major reaction, depending on the experimental conditions. Alcohols or ethers mainly give salts of carboxylic acids. Use of higher pressures of CO association with a hydrocarbon organic phase, favours coupling ...