Journal of the American Chemical Society

The metalation of some sulfur-containing organic compounds

H Gilman, FJ Webb

文献索引：Gilman; Webb Journal of the American Chemical Society, 1949 , vol. 71, p. 4062,4063

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被引用次数: 69

摘要

HOH Under corresponding conditions nuclear metalationa is effected with both diethylbarium and diethylstrontium to give metalation products which yield on carbonation, o- methylmercaptobenzoic acid. Metalations of methyl phenyl sulfide with other reagents are now reported. To determine the generality of the lateral metalation with n-butyllithium, a number of aryl methyl sulfides and higher-alkyl aryl sulfides were studied.