Chemistry Letters

GENERATION OF ARENEDIAZONIUM ION FROM MOLECULAR COMPLEX OF α-AZOHYDROPEROXIDE WITH SOLVENTS. A NEW ROUTE FOR DIAZONIUM ION

T Tezuka, S Ando

文献索引：Tezuka, Takahiro; Ando, Setsuo Chemistry Letters, 1985 , p. 1621 - 1624

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被引用次数: 8

摘要

Chemistry Letters, 19 8 5 1623 aldehyde. Photo pictures which show the change of appearance of the crystals, are attached in Fig. 1. All our observations can be explained by assuming the following mechanism. In a complex, the solvent molecules are located so as to fasten the intramolecular hy- drogen bonding^between peroxy hydrogen and ß-nitrogen of a-azohydroperoxide as in- dicated in 14. This hydrogen bond greatly diminishes the electron donating power of the ...