Chemistry Letters

GENERATION OF ARENEDIAZONIUM ION FROM MOLECULAR COMPLEX OF α-AZOHYDROPEROXIDE WITH SOLVENTS. A NEW ROUTE FOR DIAZONIUM ION

T Tezuka, S Ando

Index: Tezuka, Takahiro; Ando, Setsuo Chemistry Letters, 1985 , p. 1621 - 1624

Full Text: HTML

Citation Number: 8

Abstract

Chemistry Letters, 19 8 5 1623 aldehyde. Photo pictures which show the change of appearance of the crystals, are attached in Fig. 1. All our observations can be explained by assuming the following mechanism. In a complex, the solvent molecules are located so as to fasten the intramolecular hy- drogen bonding^between peroxy hydrogen and ß-nitrogen of a-azohydroperoxide as in- dicated in 14. This hydrogen bond greatly diminishes the electron donating power of the ...