Active metals from potassium-graphite. Zinc-graphite promoted synthesis of. beta.-hydroxy esters, homoallylic alcohols and. alpha.-methylene-. gamma.- …

…, C Trombini, A Umani-Ronchi

文献索引：Boldrini, Gian Paolo; Savoia, Diego; Tagliavini, Emilio; Trombini, Claudio; Umani-Ronchi, Achille Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4108 - 4111

全文：HTML全文

被引用次数: 63

摘要

13e 65 111 a Unless otherwise stated the reactions were carried out at 0" C, on a 10-mmol scale of carbonyl compound with a molar ratio of Zn-Gr/bromo derivative/carbonyl compound of 15/12/10. Satisfactory analytical data (* 0.4% for C and H) were obtained for all new compounds listed in the table. Yields refer to pure compounds isolated by silica gel column chromatography with hexane-ether mixtures as the eluent. See ref 22. e The ...