Tetrahedron letters

Efficient dehydrocyanation of hindered 1-substituted olefins

O Temmem, D Uguen, A De Cian, N Gruber

文献索引：Temmem; Uguen; De Cian; Gruber Tetrahedron Letters, 2002 , vol. 43, # 17 p. 3175 - 3179

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被引用次数: 4

摘要

The chlorosulfides 7 which formed quantitatively by reaction of olefins 5 with PhSCl under neutral conditions could be converted into the unsaturated nitriles 6 in good yields by sequential treatment with alkaline cyanides and MCPBA, a similar result being observed by reversing this order.