A new simple synthesis of isomerically pure α, β-unsaturated nitriles via hydroboration of alkynes

Y Masuda, M Hoshi, A Arase

文献索引：Masuda, Yuzuru; Hoshi, Masayuki; Arase, Akira Journal of the Chemical Society, Chemical Communications, 1991 , # 11 p. 748 - 749

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被引用次数: 1

摘要

Although many useful synthetic reactions using organo- boranes have been reported,l these do not include a proce- dure for synthesis of a,Cj-unsaturated nitriles. Previously we reported the first synthesis of one-carbon homologated secondary alkanenitriles from internal alkenes by use of sodium trialkylcyanoborates followed by reaction with sodium cyanide and lead(1v) acetate.* Recently we also reported a high yield synthesis of primary ...